Product Name :
2-Fluoro-1-methylpyridinium p-toluenesulfonate (CAS 58086-67-2)
Synonym :
2-Fluoro-1-methylpyridinium; Mukaiyama′s reagent
Application :
CAS:
58086-67-2
Purity:
98%
Molecular Weight:
283.32
Formula :
C6H7FN•C7H7O3S
Physical state:
Solid
solubility :
Soluble in water (hydrolyzes), DMSO, dichloromethane, and acetonitrile.
Shipping Condition :
Desiccate at 4° C
Melting point:
130-134° C (lit.)
SMILES:
C[N+]1=C(F)C=CC=C1.CC1=CC=C(C=C1)S([O-])(=O)=O
References:
:Electrospray tandem mass spectrometric study of alkyl 1-methylpyridinium ether derivatives of alcohols. | Quirke, JM. and Van Berkel, GJ. 2001. J Mass Spectrom. 36: 1294-300. PMID: 11754121Analysis of steroid estrogens in water using liquid chromatography/tandem mass spectrometry with chemical derivatizations. | Lin, YH., et al. 2007. Rapid Commun Mass Spectrom. 21: 1973-83. PMID: 17526068Separation of fatty alcohol ethoxylates by capillary zone electrophoresis and micellar electrokinetic chromatography. | Koike, R., et al. 2009. J Sep Sci. 32: 399-407. PMID: 19142913Derivatization of estrogens enhances specificity and sensitivity of analysis of human plasma and serum by liquid chromatography tandem mass spectrometry. | Faqehi, AMM., et al. 2016. Talanta. 151: 148-156. PMID: 26946022A novel diagnostic in situ derivatization kit for the simultaneous determination of 14 biomarkers of exposure to benzene, toluene, ethyl benzene and xylenes in human urine by isotope dilution liquid chromatography tandem mass spectrometry and kit optimization using response surface methodology.Buy2-Bromoimidazo[2,1-b][1,3,4]thiadiazole | Baghdady, YZ.127094-57-9 Formula and Schug, KA.PMID:33605030 2018. Anal Chim Acta. 1036: 195-203. PMID: 30253832Quantification of cannabinoids in human hair using a modified derivatization procedure and liquid chromatography-tandem mass spectrometry. | Al-Zahrani, MA., et al. 2021. Drug Test Anal. 13: 1095-1107. PMID: 33491296An LC-MS/MS method for the simultaneous quantification of 32 steroids in human plasma. | Šimková, M., et al. 2022. J Chromatogr B Analyt Technol Biomed Life Sci. 1201-1202: 123294. PMID: 35623176Stability of sample extracts of vitamin D3 metabolites after chemical derivatization for LC-MS/MS analysis. | Alexandridou, A. and Volmer, DA. 2023. Anal Bioanal Chem. 415: 327-333. PMID: 36342509Comparing derivatization reagents for quantitative LC-MS/MS analysis of a variety of vitamin D metabolites. | Alexandridou, A., et al. 2023. Anal Bioanal Chem.. PMID: 37219579A convenient synthesis of 2-azetidinones via 2-fluoro-1-methylpyridinium p-toluenesulfonate | , et al. (2013). Monatshefte für Chemie – Chemical Monthly. volume 144,: pages 1021–1025.Characteristics of the Stable Free Radical Polymerization of Styrene in the Presence of 2-Fluoro-1-methylpyridinium p-Toluenesulfonate | Peter G. Odell, Richard P. N. Veregin, Lora M. Michalak, and Michael K. Georges. 1997. Macromolecules. , 30, 8,: 2232–2237.Characterization of Polyimides by Combining Mass Spectrometry and Selective Chemical Reaction | Renata Murgasova, David M. Hercules, and James R. Edman. 2004,. Macromolecules. 37, 15: , 5732–5740.Selective detection of organic compounds on modified polymer surfaces using TOF-SIMS in combination with derivatization | M Kwon, Y Lee, Y Kim, S Han, H Kim – Applied surface science, 2006 – Elsevier. 30 July 2006,. Applied Surface Science. Volume 252, Issue 19,: Pages 6689-6692.